Understanding Selenium Mobility by Sorption and Extraction Processes in Surface Coal Mine Spoils

Understanding Selenium Mobility by Sorption and Extraction Processes in Surface Coal Mine Spoil

Surface coal mine spoil was studied to evaluate selenium (Se) mobility and solubility using batch experiments, column-Ieachmg techniques, and sequential and individual extraction processes. Both selenite and selenate followed linear isotherm patterns at relatively lower Se treatments, whereas over a broader solution Se concentraton range the sorption mechanism followed the Lanpuir model. The va...

Geochemical Processes Affecting the Mobility of Dissolved Selenium in Surface Coal Mine Backfill Environments

During surface Fadlelmawla', K.J. Reddf, and G.F. Vance3 coal mining, rock material overlying the coal is redistsibuted with respect to its original stratigraphic position. Oxidation of the redistributed backfill material may release dissolved selenium (Se) to groundwater in backfill systems. This study was initiated to examine the chemistry of Se in the groundwater backfill environment. Both b...

Modeling Selenite Sorption in Reclaimed Coal Mine Soil Materials

A GIS-based decision support system for revegetation and reclamation of Opencast Coal Mine spoils

Abandoned coal mine spoils can result in severe pollution and have aesthetic on the local environment. A range of reclamation techniques is available for substrate but only through the use of vegetation to stabilize coal mine spoils can complete long-term rehabilitation be achieved. Experimentation has been undertaken at coal mine sites to attempt to elucidate and overcome limitations to vegeta...

Thermodynamical Studies of Irreversible Sorption of CO2 by Wyodak Coal

Differential scanning calorimetry (DSC), temperature programmed desorption mass spectrometry (TPD-MS) and small angle neutron scattering (SANS) were used to investigate CO2 uptake by the Wyodak coal. Adsorption of carbon dioxide on Wyodak coal was studied by DSC. The exotherms evident at low temperatures are associated with the uptake of CO2 suggesting that carbon diox...